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Copper incorporated nanorod like mesoporous silica for one pot aerobic oxidative synthesis of pyridines

Paper ID Volume ID Publish Year Pages File Format Full-Text
49911 46773 2015 6 PDF Available
Title
Copper incorporated nanorod like mesoporous silica for one pot aerobic oxidative synthesis of pyridines
Abstract

•Synthesis of copper incorporated mesoporous silica nanorod catalyst•Nanorod silica possesses pores of dimensions of 2–4 nm.•One pot aerobic oxidative synthesis of pyridines using the Cu/SiO2 catalyst•Environmentally benign oxidation process

Copper incorporated nano-rod like mesoporous silica catalyst was synthesized, characterized by N2 adsorption, HRTEM–EDX, XRD, AAS, XPS and TPD-NH3 analyses and applied in the one-pot aerobic oxidative synthesis of highly substituted pyridines. Both the enhanced surface acidity of copper incorporated silica and the redox property were essential for pyridine synthesis. Standard leaching experiment proved that the reaction was heterogeneous.

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Keywords
Mesoporous silica nanorod; Copper incorporated silica; Redox catalyst; Pyridines
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Copper incorporated nanorod like mesoporous silica for one pot aerobic oxidative synthesis of pyridines
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 58, 5 January 2015, Pages 97–102
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
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Full-text PDF Download
Online Support
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