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On the role of WO3 surface hydroxyl groups for the photocatalytic partial oxidation of methane to methanol

Paper ID Volume ID Publish Year Pages File Format Full-Text
49932 46773 2015 4 PDF Available
Title
On the role of WO3 surface hydroxyl groups for the photocatalytic partial oxidation of methane to methanol
Abstract

•Photocatalytic conversion of CH4 over WO3 and WO3/F was studied.•Surface fluorinated WO3 led to low yield of methanol.•Reaction pathway was proposed for the photocatalytic conversion of CH4 on WO3.

The photocatalytic partial oxidation of methane to methanol has been investigated on WO3. The surface fluorination of the catalyst has given an insight on the reaction mechanism which proceeds mainly through the interaction with surface hydroxyl groups.

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Keywords
OKKJLVBELUTLKV-UHFFFAOYSA-NSurface fluorinated WO3; Photocatalysis; CH4 conversion; Mechanism
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On the role of WO3 surface hydroxyl groups for the photocatalytic partial oxidation of methane to methanol
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 58, 5 January 2015, Pages 200–203
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
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Price was $35.95
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