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Iron oxide catalyzed reduction of acid chlorides to aldehydes with hydrosilanes

Paper ID Volume ID Publish Year Pages File Format Full-Text
50030 46777 2014 4 PDF Available
Title
Iron oxide catalyzed reduction of acid chlorides to aldehydes with hydrosilanes
Abstract

•We have developed the ion oxide catalyzed reducion of acid chlorides to aldehyds.

Iron-catalyzed reduction of acid chlorides to the corresponding aldehydes with a hydrosilane as a reducing agent has been developed. A simple mixture of a commercially available iron oxide (FeO) and tris(2,4,6-trimethoxyphenyl)phosphine (TMPP) as a catalyst realized the reduction of acid chlorides to the corresponding aldehydes under mild reaction conditions.

Graphical abstractIron-catalyzed reduction of acid chlorides to the corresponding aldehydes with a hydrosilane as a reducing agent has been developed. A simple mixture of a commercially available iron oxide (FeO) and tris(2,4,6-trimethoxyphenyl)phosphine (TMPP) as a catalyst realized the reduction of acid chlorides (1) to the corresponding aldehydes (2) under mild reaction conditions.Figure optionsDownload full-size imageDownload as PowerPoint slide

Keywords
Acid chlorides; Aldehydes; Hydrosilanes; Iron oxide; Reduction
First Page Preview
Iron oxide catalyzed reduction of acid chlorides to aldehydes with hydrosilanes
Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 50, 5 May 2014, Pages 25–28
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis