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Evaluation of the utility of lanthanide salts as catalysts for the per-O-acetylation of monosaccharides

Paper ID Volume ID Publish Year Pages File Format Full-Text
50074 46779 2012 5 PDF Available
Title
Evaluation of the utility of lanthanide salts as catalysts for the per-O-acetylation of monosaccharides
Abstract

The simple, commonly occurring salts across the lanthanide period were examined as O-acetylation catalysts for monosaccharides. It was found that regardless of the temperature or gegenion, these compounds in combination with Ac2O were highly efficient and effective in a per-O-acetylation catalysis transformation.

Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slideHighlights► Simple, readily available Lanthanide salts were excellent O-acetylation catalysts. ► Monosaccharides were per-O-acetylated in excellent yield. ► Catalytic efficiency was observed even at 0.001 mol% loading.

Keywords
Acetylation; Lanthanide salts; Polyhydroxylated; Alcohols; Monosaccharides
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Evaluation of the utility of lanthanide salts as catalysts for the per-O-acetylation of monosaccharides
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 18, 10 February 2012, Pages 32–36
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
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Price was $35.95
You save - $31
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