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Synthesis of hierarchical porous zeolite and its performance in n-heptane cracking

Paper ID Volume ID Publish Year Pages File Format Full-Text
50092 46779 2012 5 PDF Available
Title
Synthesis of hierarchical porous zeolite and its performance in n-heptane cracking
Abstract

A series of hierarchical porous zeolites (ZSM-5–ZRP-1) was synthesized by adding different contents of ZRP-1 to the procedure of hydrothermal synthesis of ZSM-5. The prepared samples were characterized by using N2 adsorption–desorption, XRD, SEM, TEM, NH3-TPD, Py-FTIR and investigated in cracking of n-heptane. The results indicate that physicochemical properties and catalytic performances of ZSM-5–ZRP-1 samples are quite different from those of HZSM-5 or ZRP-1. ZSM-5–ZRP-1 samples have a lot of mesopores and suitable amount of B + L acid sites as well as higher L/B ratio compared with HZSM-5 or ZRP-1, and also show medium acid amount and strength. These lead to a higher selectivity of olefins (ethylene plus propylene) obtained on it.

Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slideHighlights► Hierarchical zeolites (ZSM-5-ZRP-1) were synthesized by hydrothermal method. ► ZSM-5-ZRP-1 catalysts possess unique physicochemical properties. ► The enhanced activity of ZSM-5-ZRP-1 is related to its physicochemical properties.

Keywords
Hierarchical zeolite; n-Heptane; Ethylene; Propylene; Cracking
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 18, 10 February 2012, Pages 110–114
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
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Price was $35.95
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