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Efficient catalysts for benzene alkylation with olefins

Paper ID Volume ID Publish Year Pages File Format Full-Text
50107 46780 2016 6 PDF Available
Title
Efficient catalysts for benzene alkylation with olefins
Abstract

•Methyl- and ethylsilanes catalyze the benzene alkylation by ethylene and propylene.•The silanes are on a par with AlCl3 by selectivity and catalytic activity.•Catalytic activity is linearly dependent from the charges and acceptor capacities.

The experimental data of benzene alkylation with ethylene and propylene in the presence of methyl and ethylchlorosilanes are presented in this article. The catalytic activity series are determined for the methyl and ethylchlorosilanes. These compounds are found to demonstrate high catalytic activity and selectivity in the alkylation reactions and can be used in place of aluminum chloride. The computational study reveals the linear dependence between the charges, acceptor capacities and activities of the catalysts in the alkylation reactions.

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Keywords
Alkylation; Alkylchlorosilanes; Mathematical modeling; Catalysis; Quantum chemical computations
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 82, 5 July 2016, Pages 1–6
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us