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Iridium-catalyzed aerobic oxidation of alkylarenes with excellent turnover numbers

Paper ID Volume ID Publish Year Pages File Format Full-Text
50133 46781 2013 4 PDF Available
Title
Iridium-catalyzed aerobic oxidation of alkylarenes with excellent turnover numbers
Abstract

A highly efficient catalyst system has been developed for the aerobic oxidation of alkylarenes under solvent free conditions. The combination of iridium complex, nitrogen ligand and iodobenzene was found to be crucial for catalytic activity. Excellent turnover numbers were achieved for the preparation of benzoic acids and aryl ketones. This finding may provide useful clues for improving commercially important oxidation processes.

Graphical abstractA highly efficient catalyst system has been developed for the aerobic oxidation of alkylarenes under solvent free conditions. The combination of iridium complex, nitrogen ligand and iodobenzene was found to be crucial for catalytic activity. Excellent turnover numbers were achieved for the preparation of benzoic acids and aryl ketones.Figure optionsDownload full-size imageDownload as PowerPoint slideHighlights► Combination of iridium complex, nitrogen ligand and iodobenzene provided an extremely active catalyst system. ► Aerobic oxidation of alkylarenes under solvent free conditions. ► Excellent turnover numbers were achieved for the preparation of benzoic acids an aryl ketones.

Keywords
Aerobic oxidation; Alkylarenes; Iridium complex; Iodobenzene
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Iridium-catalyzed aerobic oxidation of alkylarenes with excellent turnover numbers
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 35, 5 May 2013, Pages 64–67
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
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Price was $35.95
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