fulltext.study @t Gmail

Exceptional activity for direct synthesis of phenol from benzene over PMoV@MOF with O2

Paper ID Volume ID Publish Year Pages File Format Full-Text
50140 46781 2013 4 PDF Available
Title
Exceptional activity for direct synthesis of phenol from benzene over PMoV@MOF with O2
Abstract

Three novel catalysts named as PMo12 − nVn@HKUST-1 (n = 1–3) were designed and obtained through encapsulating vanadium-doped Keggin polyoxometalates (POMs) PMo12 − n Vn into the framework HKUST-1 (also denoted as Cu3(BTC)2, MOF-199). The character structure of PMo12 − n Vn@HKUST-1 was elucidated through the single crystal XRD of PMo11V@HKUST-1. Reaction rate could be greatly enhanced by PMo12 − n Vn@HKUST-1 in liquid hydroxylation of benzene with O2. Only in 20 min, a high TOF (44.2 h− 1) of PMo9V3@HKUST-1 was obtained.

Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slideHighlights► Three novel catalysts PMo12-nVn@HKUST-1 (n = 1–3) were designed and obtained. ► Reaction rate could be greatly enhanced in liquid hydroxylation of benzene. ► Only in 20 min, a high TOF (44.2 h− 1) of PMo9V3@HKUST-1 was obtained.

Keywords
Polyoxometalates; MOFs; Oxygen; Benzene; Phenol
First Page Preview
Exceptional activity for direct synthesis of phenol from benzene over PMoV@MOF with O2
Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 35, 5 May 2013, Pages 101–104
Authors
, , , , , ,
Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis