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One-pot conversion of cellulose to isosorbide using supported metal catalysts and ion-exchange resin

Paper ID Volume ID Publish Year Pages File Format Full-Text
50207 46784 2015 5 PDF Available
Title
One-pot conversion of cellulose to isosorbide using supported metal catalysts and ion-exchange resin
Abstract

•Cellulose was directly converted into isosorbide in water.•Supported ruthenium catalyst with ion-exchange resin showed high activity.•The maximum yield of isosorbide from cellulose was 55.8%.

One-pot conversion of cellulose to isosorbide was investigated by supported metal catalysts and ion-exchange resin in water. The maximum isosorbide yield using supported platinum catalysts and Amberlyst 70 was less than 30%. The isosorbide yield drastically increased with supported ruthenium catalysts instead of supported platinum catalysts and it also increased with the loading of ruthenium on carbon support. One-pot conversion of cellulose to isosorbide by 4 wt.% ruthenium catalyst and Amberlyst 70 proceeded with isosorbide yield of 55.8%.

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Keywords
Biomass conversion; Cellulose; Isosorbide; Sugar alcohol; Heterogeneous catalysis
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One-pot conversion of cellulose to isosorbide using supported metal catalysts and ion-exchange resin
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 67, 5 July 2015, Pages 59–63
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
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Full-text PDF Download
Online Support
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