fulltext.study @t Gmail

Desilication of TS-1 zeolite for the oxidation of bulky molecules

Paper ID Volume ID Publish Year Pages File Format Full-Text
50252 46786 2014 5 PDF Available
Title
Desilication of TS-1 zeolite for the oxidation of bulky molecules
Abstract

•Desilication of TS-1 gives rise to hierarchical materials with bimodal PSD.•Desilicated TS-1 exhibits a large BET surface area and well-developed mesoporosity.•Desilicated TS-1 remains the activity of the original TS-1 for small molecules.•Desilicated TS-1 shows an improvement for the oxidation of bulky molecules.

A series of modified TS-1 samples have been produced by desilication of the original TS-1 (4 wt.% Ti) using a chemical treatment with NaOH. Desilicated TS-1 zeolites exhibit a large BET surface area together with a well-developed mesoporosity. The hierarchical catalysts from desilication of TS-1 zeolite show a good catalytic activity for the oxidation of small molecules and a significantly higher activity for the oxidation of bulky molecules.

Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slide

Keywords
Desilication; Hierarchical catalysts; TS-1; Epoxidation reactions
First Page Preview
Desilication of TS-1 zeolite for the oxidation of bulky molecules
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us
Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 44, 10 January 2014, Pages 35–39
Authors
, , , , ,
Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us