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2-Methyltetrahydrofuran: Sustainable solvent for ruthenium-catalyzed olefin metathesis

Paper ID Volume ID Publish Year Pages File Format Full-Text
50262 46786 2014 5 PDF Available
Title
2-Methyltetrahydrofuran: Sustainable solvent for ruthenium-catalyzed olefin metathesis
Abstract

•New Hoveyda-type catalysts are presented.•Use of 2-methyltetrahydrofuran as green solvent for olefin metathesis is shown.•Temperature and solvent dependence on the activity of catalyst are presented.•New catalysts show superior activity in 2-methyltetrahydrofuran.

Applicability of 2-methyltetrahydrofuran for olefin metathesis was examined with a set of ruthenium Hoveyda-type second generation catalysts. Influence of temperature was studied and the results were compared with those obtained in classical solvents for metathesis: dichloromethane and toluene.

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Keywords
Olefin metathesis; Ruthenium complexes; Hoveyda type catalysts; 2-Methyltetrahydrofuran
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2-Methyltetrahydrofuran: Sustainable solvent for ruthenium-catalyzed olefin metathesis
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 44, 10 January 2014, Pages 80–84
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
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Price was $35.95
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Price after discount Only $4.95
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