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Highly efficient aerobic epoxidation of cyclic olefins in mild conditions by a novel binuclear manganese(II) complex containing N-(4-nitrophenyl)picolinamide ligand

Paper ID Volume ID Publish Year Pages File Format Full-Text
50278 46787 2015 4 PDF Available
Title
Highly efficient aerobic epoxidation of cyclic olefins in mild conditions by a novel binuclear manganese(II) complex containing N-(4-nitrophenyl)picolinamide ligand
Abstract

•Structural study of a novel binuclear Mn(II) complex•Evaluation of catalyst in Mukaiyama epoxidation reaction•Eliciting the higher efficiency in aerobic epoxidation of cyclic olefins

A novel binuclear Mn(II) complex based on a para-nitro substituted amidic ligand (N-(4-nitrophenyl)picolinamide) has been synthesized and characterized by X-ray crystallography. This complex shows a high degree of conversion and epoxide selectivity in Mukaiyama aerobic epoxidation reactions of cyclic olefins in mild conditions.

Keywords
Mukaiyama aerobic epoxidation reactions; Mn(II) complex; Amidic ligands
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Highly efficient aerobic epoxidation of cyclic olefins in mild conditions by a novel binuclear manganese(II) complex containing N-(4-nitrophenyl)picolinamide ligand
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 65, 5 May 2015, Pages 72–75
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
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Price was $35.95
You save - $31
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Any Questions? feel free to contact us