fulltext.study @t Gmail

Highly active palladium nanoparticles immobilized on NH2-MIL-125 as efficient and recyclable catalysts for Suzuki–Miyaura cross coupling reaction

Paper ID Volume ID Publish Year Pages File Format Full-Text
50282 46787 2015 5 PDF Available
Title
Highly active palladium nanoparticles immobilized on NH2-MIL-125 as efficient and recyclable catalysts for Suzuki–Miyaura cross coupling reaction
Abstract

•Pd NPs were deposited on NH2-MIL-125 and characterized.•The catalyst promoted Suzuki coupling without external additives.•The catalyst was recovered easily and reused for at least four runs.

Pd nanoparticles were deposited successfully on a porous metal-organic framework NH2-MIL-125, and characterized by powder X-ray diffraction, thermogravimetric analysis, N2 adsorption–desorption isotherms, X-ray photoelectron spectroscopy, and field emission transmission electron microscopy. The as-synthesized NH2-MIL-125-supported palladium nanoparticles exhibited excellent heterogeneous catalytic performance towards Suzuki cross coupling between the aryl chlorides and arylboronic acids. The catalyst could be reused at least four times under the optimized conditions with only a minor decrease in catalytic activity. The Sheldon test confirmed the heterogeneity of the catalyst.

Keywords
Metal-organic frameworks; Palladium nanoparticles; Suzuki coupling; Titanium; Heterogeneous catalyst
First Page Preview
Highly active palladium nanoparticles immobilized on NH2-MIL-125 as efficient and recyclable catalysts for Suzuki–Miyaura cross coupling reaction
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us
Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 65, 5 May 2015, Pages 91–95
Authors
, ,
Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us