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Efficient and eco-compatible transition metal-free Oppenauer-type oxidation of alcohols

Paper ID Volume ID Publish Year Pages File Format Full-Text
50301 46788 2014 5 PDF Available
Title
Efficient and eco-compatible transition metal-free Oppenauer-type oxidation of alcohols
Abstract

•Cheap and safe NaOtBu catalytically promotes dehydrogenative oxidation of alcohols.•The H-acceptor used is commercially available and cheap.•The oxidation method is transition metal-free and ligand-free.

Catalytic amounts of cheap, non-toxic, easy-to-handle and non-sensitive sodium tert-butoxide are able to promote the dehydrogenative oxidation of a wide array of secondary alcohols using inexpensive benzophenone as the H-acceptor. The corresponding ketones, highly important intermediates and targets throughout life and material sciences, are very selectively obtained under mild conditions.

Keywords
Alcohol; Oxidation; Oppenauer; Sodium tert-butoxide; Ketone; Catalysis
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Efficient and eco-compatible transition metal-free Oppenauer-type oxidation of alcohols
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 47, 5 March 2014, Pages 58–62
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us