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Highly selective low-temperature hydrogenation of furfuryl alcohol to tetrahydrofurfuryl alcohol catalysed by hectorite-supported ruthenium nanoparticles

Paper ID Volume ID Publish Year Pages File Format Full-Text
50313 46789 2011 4 PDF Available
Title
Highly selective low-temperature hydrogenation of furfuryl alcohol to tetrahydrofurfuryl alcohol catalysed by hectorite-supported ruthenium nanoparticles
Abstract

Metallic ruthenium nanoparticles intercalated in hectorite (particle size ~ 4 nm) were found to catalyse the hydrogenation of furfuryl acohol to give tetrahydrofurfuryl alcohol in methanolic solution under mild conditions. The best results were obtained at 40 °C under a hydrogen pressure of 20 bar (conversion 100%, selectivity > 99%). After a total turnover number of 1423, the hectorite supported ruthenium nanoparticles are deactivated but can be recycled and regenerated.

Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slideResearch highlights► Ruthenium nanoparticles intercalated in hectorite are found to efficiently catalyze the hydrogenation of furfuryl alcohol at low temperatures. ► The best results were obtained at 40 °C under a hydrogen pressure of 20 bar (conversion 100%, selectivity > 99%, TON = 1423). ► Hectorite-supported ruthenium nanoparticles can be recycled and regenerated.

Keywords
Ruthenium nanoparticles; Ruthenium-modified hectorite; Furfuryl alcohol hydrogenation
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Highly selective low-temperature hydrogenation of furfuryl alcohol to tetrahydrofurfuryl alcohol catalysed by hectorite-supported ruthenium nanoparticles
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 12, Issue 15, 15 September 2011, Pages 1428–1431
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us