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Catalytic hydrocarbon oxidation by iron complex of 5,10,15-tris(difluorophenyl)corrole via activation of hydroperoxides

Paper ID Volume ID Publish Year Pages File Format Full-Text
50334 46790 2013 5 PDF Available
Title
Catalytic hydrocarbon oxidation by iron complex of 5,10,15-tris(difluorophenyl)corrole via activation of hydroperoxides
Abstract

The catalytic properties of 5,10,15-tris(difluorophenyl)iron(IV) corrole complex [(tdfc)FeIVCl] (1) with tert-butylhydroperoxide as the terminal oxidant was evaluated. The 1/t-BuOOH system has been found to catalyze the oxidation of alkanes, alkenes, alkylbenzene and alcohols at room temperature. The homolytic cleavage of the OO bond of tert-butylhydroperoxide by catalyst 1 was observed and the oxygenates have been shown to be derived from organoperoxides. Selective hydroxylation of unactivated CH bonds of alkanes has also been realized using catalyst 1 with m-chloroperbenzoic acid as the oxidant.

Graphical abstractCatalytic oxidation of hydrocarbons was studied with tert-butylhydroperoxide and m-chloroperbenzoic acid as oxidant at room temperature under argon and in air using novel 5,10,15-tris(difluorophenyl) iron(IV) corrole complex [FeIV(tdfc)Cl] as catalyst.Figure optionsDownload full-size imageDownload as PowerPoint slideHighlights► Synthesis of Iron(IV) complex of 5,10,15-tris(difluorophenyl) corrole ► Catalytic hydrocarbon oxidation at room temperature by the iron(IV) catalyst ► Activation of alkyl hydroperoxide by iron corrole ► Selective hydroxylation of alkanes by m-CPBA

Keywords
5,10,15-tris(difluorophenyl)iron(IV) corrole; Catalysis; Oxygenation; t-Butyl hydroperoxide; Cyclohexylhydroperoxide
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Catalytic hydrocarbon oxidation by iron complex of 5,10,15-tris(difluorophenyl)corrole via activation of hydroperoxides
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 32, 5 February 2013, Pages 23–27
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
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Price was $35.95
You save - $31
Price after discount Only $4.95
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