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Nano-ruthenium particles supported on a core-shell shuttle: As an efficient lipophilic catalyst for the aerobic oxidation of biomass-derived 5-(Hydroxymethyl)furfural

Paper ID Volume ID Publish Year Pages File Format Full-Text
50356 46792 2015 5 PDF Available
Title
Nano-ruthenium particles supported on a core-shell shuttle: As an efficient lipophilic catalyst for the aerobic oxidation of biomass-derived 5-(Hydroxymethyl)furfural
Abstract

•The catalyst has a unique nano-sized core-shell structure.•The catalyst is first used in the oxidation of 5-(Hydroxymethyl)furfural.•The catalyst we synthesized is lipophilic, thus resulting in higher conversions.•We examined various kinds of solvents and carriers for the oxidation.

We synthesize a novel mesoporous core-shell shuttle, which is lipophilic. It was used as the precursor loading the ruthenium nanoparticles to afford the catalyst for the aerobic oxidation of 5-(Hydroxymethyl)furfural. The whole oxidation process with the catalyst is highly efficient and chemo-selective. The shuttle can take Ru nanoparticles (RuNP) to the organic phase for catalyzing and make the reaction homogeneous resulting in a high conversion of 5-(Hydroxymethyl)furfural. The catalyst is stable and can be reused for at least five runs.

Keywords
OUEFSUWBFPAPBP-UHFFFAOYSA-NCore-shell; Ru; Oxidation; 5-(Hydroxymethyl)furfural; Lipophilic
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Nano-ruthenium particles supported on a core-shell shuttle: As an efficient lipophilic catalyst for the aerobic oxidation of biomass-derived 5-(Hydroxymethyl)furfural
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 63, 10 March 2015, Pages 21–25
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us