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Synthesis of a Ni2P catalyst supported on anatase–TiO2 whiskers with high hydrodesulfurization activity, based on triphenylphosphine

Paper ID Volume ID Publish Year Pages File Format Full-Text
50431 46794 2014 4 PDF Available
Title
Synthesis of a Ni2P catalyst supported on anatase–TiO2 whiskers with high hydrodesulfurization activity, based on triphenylphosphine
Abstract

•Anatase-TiO2 whiskers supported Ni2P catalyst was synthetized by using PPh3.•The structure of anatase-TiO2 whiskers unchanged and suppressed formation of TiPO4.•The catalyst Ni2P–PPh3 showed higher HDS activity than that of the Ni2P–TPR.

A solution method for preparing a Ni2P catalyst supported on anatase–TiO2 whiskers (Ni2P–PPh3) based on low cost triphenylphosphine (PPh3) is described. This approach suppressed the formation of the TiPO4 phase. The synthesis temperature is modest (603 K). The Ni2P–PPh3 catalyst did not modify the anatase–TiO2 phase in any way, and it showed much higher hydrodesulfurization activity than the same catalyst prepared by the conventional TPR method.

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Keywords
Nickel phosphide (Ni2P); Triphenylphosphine (PPh3); Anatase–TiO2 whiskers; Hydrodesulfurization (HDS)
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Synthesis of a Ni2P catalyst supported on anatase–TiO2 whiskers with high hydrodesulfurization activity, based on triphenylphosphine
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 43, 5 January 2014, Pages 151–154
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
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