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Mild oxidative alkane functionalization with peroxides in the presence of ferrocene

Paper ID Volume ID Publish Year Pages File Format Full-Text
50458 46795 2013 5 PDF Available
Title
Mild oxidative alkane functionalization with peroxides in the presence of ferrocene
Abstract

Ferrocene in an unexpected emploi: alkanes can be efficiently oxygenated by H2O2 in the presence of catalytic amounts of this well-known organometallic compound in combination with pyrazine-2-carboxylic acid or 2,2′-bipyridine. Saturated hydrocarbons, RH, are also transformed into carboxylic acids, RCOOH, when reacted with the ferrocene/CO/S2O82 −/H2O system in acetonitrile solution.

Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slideHighlights► Combination H2O2/ferrocene/pyrazinic acid oxygenates alkanes. ► Turnover numbers were up to 1200. ► The ferrocene/CO/S2O82 −/H2O system transforms RH into RCOOH. ► The oxidation proceeds with the participation of free radicals.

Keywords
Alkanes; Homogeneous catalysis; Hydrogen peroxide; Hydrocarboxylation; Hydroperoxidation; Iron complexes
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Mild oxidative alkane functionalization with peroxides in the presence of ferrocene
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 31, 10 January 2013, Pages 32–36
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
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