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Aqueous-phase hydrogenation of biomass-derived itaconic acid to methyl-γ-butyrolactone over Pd/C catalysts: Effect of pretreatments of active carbon

Paper ID Volume ID Publish Year Pages File Format Full-Text
50548 46801 2015 5 PDF Available
Title
Aqueous-phase hydrogenation of biomass-derived itaconic acid to methyl-γ-butyrolactone over Pd/C catalysts: Effect of pretreatments of active carbon
Abstract

•The Pd/C catalyst is efficient for itaconic acid hydrogenation.•The methyl-γ-butyrolactone yield depends on the pretreatment of active carbon.•The catalysts with carbon copretreated with HNO3 and NaClO show superior activity.•The yield of methyl-γ-butyrolactone reaches 89.5% over optimized catalyst.

The effect of active carbon pretreatment on the catalytic performance of Pd/C catalysts in the hydrogenation of itaconic acid was studied. The catalysts were prepared by deposition–precipitation and characterized by XRD, BET, NH3-TPD, TEM and FT-IR. Due to the modification of the surface functional groups, surface structure and surface acidities of active carbon via pretreatment, the Pd/C catalysts showed varied catalytic performances. High dispersion and uniform particles were conducive to the excellent activity of Pd/C catalyst with support copretreated with HNO3 and NaClO, which exhibited 89.5% selectivity towards methyl-γ-butyrolactone at 180 °C, 4 MPa H2 for 20 h.

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Keywords
Biomass; Itaconic acid; Methyl-γ-butyrolactone; Hydrogenation; Pd/CQGLBZNZGBLRJGS-UHFFFAOYSA-N; ALZLTHLQMAFAPA-UHFFFAOYSA-N; LVHBHZANLOWSRM-UHFFFAOYSA-N; WXUAQHNMJWJLTG-UHFFFAOYSA-N
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Aqueous-phase hydrogenation of biomass-derived itaconic acid to methyl-γ-butyrolactone over Pd/C catalysts: Effect of pretreatments of active carbon
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 61, 10 February 2015, Pages 92–96
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us