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Assembly of Ti/Ce metal-to-metal charge-transfer moieties on a graphene oxide surface and their catalytic activity

Paper ID Volume ID Publish Year Pages File Format Full-Text
50561 46802 2013 5 PDF Available
Title
Assembly of Ti/Ce metal-to-metal charge-transfer moieties on a graphene oxide surface and their catalytic activity
Abstract

For the first time, Ti/Ce metal-to-metal charger-transfer (MMCT) moieties were covalently assembled onto the surface of graphene oxide (GO). The hybrid component material of Ti/Ce–GO exhibited the enhanced absorption in visible light with a tail extending up to 800 nm, also much higher photocatalytic activity in the degradation of Rhodamine B under the irradiation of visible light.

Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slideHighlights► Ti/Ce MMCT moieties were successfully assembled onto the surface of graphene oxide. ► Ti/Ce–GO materials exhibited the intense absorption in visible light. ► The absorption induced by photoexcited transition of Ti/Ce MMCT system was enhanced. ► Much higher photocatalytic activity irradiated by visible light was obtained.

Keywords
Graphene oxide; Metal-to-metal charge transfer; Photocatalytic activity
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 33, 5 March 2013, Pages 24–28
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
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