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Partial oxidation of methane with nitrous oxide forms synthesis gas over cobalt exchanged ZSM-5

Paper ID Volume ID Publish Year Pages File Format Full-Text
50726 46811 2014 5 PDF Available
Title
Partial oxidation of methane with nitrous oxide forms synthesis gas over cobalt exchanged ZSM-5
Abstract

•Cobalt is loaded over ZSM-5 support.•Reactivity of CH4 with N2O over Co-ZSM-5 forms synthesis gas (CO + H2).•Co2 + sites are the proposed active sites for H2 formation (synthesis gas).

Synthesis gas (CO + H2) is a versatile and significant resource. In this communication we show that cobalt loaded on ZSM-5 (Co-ZSM-5) catalyses the formation of synthesis gas from CH4, under partial oxidation conditions using N2O as oxidant. With O2 as oxidant over the same Co-ZSM-5 catalyst, cobalt on alumina and Fe-ZSM-5, only COx and H2O are formed. Isolated Co2 + sites in the ZSM-5 support are proposed as the active sites for H2 (synthesis gas) formation.

Keywords
Co-ZSM-5; Partial oxidation; N2O; CH4
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Partial oxidation of methane with nitrous oxide forms synthesis gas over cobalt exchanged ZSM-5
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 53, 5 August 2014, Pages 42–46
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
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