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Highly selective oxidation of organosilanes with a reusable nanoporous silver catalyst

Paper ID Volume ID Publish Year Pages File Format Full-Text
50728 46811 2014 4 PDF Available
Title
Highly selective oxidation of organosilanes with a reusable nanoporous silver catalyst
Abstract

•Nanoporous silver has been used as the catalyst for the oxidation of silanes.•Organosilyl-ethers have been prepared by the similar way.•The kinetic studies were carried out and the possible mechanism was got.

Room temperature highly selective oxidation of organosilanes to organosilanols and organosilyl ethers is achieved in liquid-phase with dealloyed nanoporous silver catalysts. In both cases, aromatic and aliphatic silanes can be effectively converted into the corresponding silanols and silyl ethers by using water and alcohols as oxidant, respectively. Moreover, hydrogen gas is the only by-product and the catalyst can be recycled for several times without evident loss of activity and selectivity.

Graphical abstractRoom temperature highly selective oxidation of organosilanes to organosilanols and organosilyl ethers is achieved in liquid-phase with dealloyed nanoporous silver catalysts.Figure optionsDownload full-size imageDownload as PowerPoint slide

Keywords
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Highly selective oxidation of organosilanes with a reusable nanoporous silver catalyst
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 53, 5 August 2014, Pages 53–56
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
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Full-text PDF Download
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