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Dehydrogenation of alcohols under ambient atmosphere by a recyclable sol–gel encaged iridium pincer catalyst

Paper ID Volume ID Publish Year Pages File Format Full-Text
50782 46813 2012 3 PDF Available
Title
Dehydrogenation of alcohols under ambient atmosphere by a recyclable sol–gel encaged iridium pincer catalyst
Abstract

We demonstrate that a sol–gel entrapped iridium-pincer catalyst 1 is capable of promoting acceptorless dehydrogenation of primary and secondary alcohols. Although the dehydrogenations by the non-heterogenized catalyst are faster than by the sol–gel encaged complex, recyclability and significant stabilization of the organometallic species toward non-inert conditions represent a clear advantage from the environmental and practical points of view.

Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slideHighlights► The first sol-gel entrapped pincer catalyst for alcohol dehydrogenation is shown. ► The heterogenized catalyst is robust and operates under ambient conditions. ► The catalyst is recyclable and can be applied up to 5 runs.

Keywords
Sol–gel processes; sp3-Metalated pincer complex; Acceptorless dehydrogenation; Iridium
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Dehydrogenation of alcohols under ambient atmosphere by a recyclable sol–gel encaged iridium pincer catalyst
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 20, 5 April 2012, Pages 68–70
Authors
, , , ,
Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us