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Mild oxidation of hydrocarbons catalyzed by iron corrole with tert-butylhydroperoxide

Paper ID Volume ID Publish Year Pages File Format Full-Text
50795 46814 2010 4 PDF Available
Title
Mild oxidation of hydrocarbons catalyzed by iron corrole with tert-butylhydroperoxide
Abstract

Catalytic alkane and alkene oxidation by iron complex of 5,10,15 tris-(pentafluorophenyl)corrole, using 70% tert-butyl hydroperoxide as oxidant at room temperature is reported for the very first time. Involvement of freely diffusing radicals in the oxidizing system is observed. A reaction mechanism is proposed based on the experimental results.

Keywords
Iron corrole; Catalysis; Oxygenation; t-butyl hydroperoxide
First Page Preview
Mild oxidation of hydrocarbons catalyzed by iron corrole with tert-butylhydroperoxide
Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 11, Issue 12, 1 July 2010, Pages 1008–1011
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis