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Clean and selective oxidation of alcohols with n-Bu4NHSO5 catalyzed by ionic liquid immobilized TEMPO in ionic liquid [bmim][PF6]

Paper ID Volume ID Publish Year Pages File Format Full-Text
50797 46814 2010 4 PDF Available
Title
Clean and selective oxidation of alcohols with n-Bu4NHSO5 catalyzed by ionic liquid immobilized TEMPO in ionic liquid [bmim][PF6]
Abstract

An efficient oxidation of alcohols with tetra-n-butylammonium peroxymonosulfate catalyzed by ionic liquid immobilized TEMPO in ionic liquid [bmim][PF6] was reported. TEMPO-IL serves as a homogeneous catalyst to enhance the reaction remarkably. The oxidation proceeded to afford aldehydes or ketones in excellent yields and high selectivity without remarkable over-oxidation to carboxylic acids. It is noteworthy to mention that the catalyst and solvent could easily be recycled and reused without loss of activity. A possible mechanism for the oxidation is proposed.

Keywords
Alcohol; TEMPO; Ionic liquid; Oxidation
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Clean and selective oxidation of alcohols with n-Bu4NHSO5 catalyzed by ionic liquid immobilized TEMPO in ionic liquid [bmim][PF6]
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 11, Issue 12, 1 July 2010, Pages 1017–1020
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
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Any Questions? feel free to contact us