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A dinuclear manganese(II) complex with 2,6-pyridinedicarboxylate: Preparation, crystal structure and oxygen evolution activity in the presence of oxone

Paper ID Volume ID Publish Year Pages File Format Full-Text
50801 46814 2010 4 PDF Available
Title
A dinuclear manganese(II) complex with 2,6-pyridinedicarboxylate: Preparation, crystal structure and oxygen evolution activity in the presence of oxone
Abstract

A dinuclear complex of Mn(II) with 2,6-pyridinedicarboxylate, [Mn2(dipic)2(H2O)6].2H2dipic, where dipic = 2,6-pyridinedicarboxylate, has been synthesized and characterized by elemental analysis, IR, EPR, electronic absorption spectroscopy, electrochemistry and single-crystal X-ray diffraction. The complex acts as an oxygen evolving complex with oxone (2KHSO5.KHSO4 .K2SO4) as primary oxidant in aqueous solution with a turnover number of ∼ 5 (mol of O2/mol of the complex).

Keywords
2,6-pyridinedicarboxylate; Manganese; Oxygen evolving complex; Spectroscopic properties; Oxone
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A dinuclear manganese(II) complex with 2,6-pyridinedicarboxylate: Preparation, crystal structure and oxygen evolution activity in the presence of oxone
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 11, Issue 12, 1 July 2010, Pages 1032–1035
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
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Price was $35.95
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