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Thio-photocatalysis II: Synthesis of dioctylsulfide in the liquid phase by the photocatalytic addition of 1-octanethiol on 1-octene

Paper ID Volume ID Publish Year Pages File Format Full-Text
50927 46822 2010 4 PDF Available
Title
Thio-photocatalysis II: Synthesis of dioctylsulfide in the liquid phase by the photocatalytic addition of 1-octanethiol on 1-octene
Abstract

Photocatalytic synthesis of dioctylsulfide has been performed at room temperature in liquid phase by addition of 1-octanethiol on 1-octene in contact with illuminated TiO2. Under inert atmosphere, dioctylsulfide is selectively obtained whereas in the presence of oxygen high selectivity in n-dioctylsulfide has vanished. This study illustrates the potential of photocatalysis for the production of thio-compounds.

Keywords
Thiochemistry; Photocatalysis; Sulfides; Titania; Dioctylsulfide
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Thio-photocatalysis II: Synthesis of dioctylsulfide in the liquid phase by the photocatalytic addition of 1-octanethiol on 1-octene
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 11, Issue 14, 25 August 2010, Pages 1116–1119
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
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Price was $35.95
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Price after discount Only $4.95
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