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Catalytic conversion of C12–C14 primary alcohols mixture into long-chain ketones

Paper ID Volume ID Publish Year Pages File Format Full-Text
50933 46822 2010 5 PDF Available
Title
Catalytic conversion of C12–C14 primary alcohols mixture into long-chain ketones
Abstract

A charge of raw primary alcohols of high molecular weight from commercial plant was transformed into long-chain ketones fraction of potential commercial use. In this continuous flow method LaMnO3/La–Al2O3 catalyst was used. At 420 °C and a normal pressure mixture of 74.2 wt.% C12 and 25.8 wt.% C14 primary alcohols and toluene (weight ratio alcohols:toluene = 1:1) was converted into ketones with 73.4% yield in relation to the theoretical value. Ketones were analyzed by TLC, NMR and GC-MSD.

Keywords
Ketonization; Lanthanum manganite; Manganese; Alcohol fraction; Ketone fraction
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Catalytic conversion of C12–C14 primary alcohols mixture into long-chain ketones
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 11, Issue 14, 25 August 2010, Pages 1143–1147
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us