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MIL-101 metal–organic framework: A highly efficient heterogeneous catalyst for oxidative cleavage of alkenes with H2O2

Paper ID Volume ID Publish Year Pages File Format Full-Text
50964 46824 2012 5 PDF Available
Title
MIL-101 metal–organic framework: A highly efficient heterogeneous catalyst for oxidative cleavage of alkenes with H2O2
Abstract

In the present work, a new and efficient method for direct oxidation of alkenes to carboxylic acids with H2O2 catalyzed by metal–organic framework MIL-101 is reported. In this transformation, the MIL-101 catalyzes the oxidation reactions by framework nodes and acts as a heterogeneous and reusable catalyst. The structure of MIL-101 was stable after three catalytic cycles.

Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slideHighlights► MIL-101 metal–organic framework was prepared. ► This heterogeneous catalyst was used for oxidation of alkenes with H2O2. ► The corresponding carboxylic acids were obtained. ► The catalyst was reusable.

Keywords
Metal–organic framework; MIL-101; Hydrogen peroxide; Oxidation; Carboxylic acid
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MIL-101 metal–organic framework: A highly efficient heterogeneous catalyst for oxidative cleavage of alkenes with H2O2
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 17, 5 January 2012, Pages 18–22
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us