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Cinchona-modified Ru catalysts for enantioselective heterogeneous hydrogenation of aromatic ketones

Paper ID Volume ID Publish Year Pages File Format Full-Text
51002 46825 2010 4 PDF Available
Title
Cinchona-modified Ru catalysts for enantioselective heterogeneous hydrogenation of aromatic ketones
Abstract

In this communication, we describe the highly enantioselective heterogeneous hydrogenation of aromatic ketones catalyzed by Ph3P stabilized Ru/γ-Al2O3, and modified by chiral diamines derived from cinchona alkaloids. A broad range of aromatic ketones over this catalyst can be hydrogenated to the corresponding alcohols with impressive enantioselectivity.

Keywords
Alkaloids; Asymmetric catalysis; Ruthenium; Ketones; Supported catalysts
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Cinchona-modified Ru catalysts for enantioselective heterogeneous hydrogenation of aromatic ketones
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 11, Issue 7, 10 March 2010, Pages 584–587
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us