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Selective conversion of glycerol to acetol over sodium-doped metal oxide catalysts

Paper ID Volume ID Publish Year Pages File Format Full-Text
51010 46825 2010 4 PDF Available
Title
Selective conversion of glycerol to acetol over sodium-doped metal oxide catalysts
Abstract

Glycerol conversion to produce 1-hydroxypropan-2-one (acetol) has been investigated over 5 wt.% Na-doped on CeO2, Al2O3, ZrO2 and Ga2O3. The observed performance demonstrates that the 5 wt.% Na-doped CeO2 is one of the best catalysts to exhibit high conversion and high selectivity for acetol formation among catalysts tested in this work. XRD patterns of Na-doped catalysts showed that no alteration of metal oxide phases was observed after sodium doping. Temperature-programmed desorption (TPD) of CO2 and NH3 show the optimum number of base and acid sites on 5 wt.% Na-doped CeO2.

Keywords
Glycerol conversion; Acetol; Na loaded metal oxide catalysts; Continuous fix bed reactor
First Page Preview
Selective conversion of glycerol to acetol over sodium-doped metal oxide catalysts
Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 11, Issue 7, 10 March 2010, Pages 620–623
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis