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Thermoregulated phase-transfer rhodium nanoparticle catalyst for hydrogenation in an aqueous/organic biphasic system

Paper ID Volume ID Publish Year Pages File Format Full-Text
51088 46829 2010 5 PDF Available
Title
Thermoregulated phase-transfer rhodium nanoparticle catalyst for hydrogenation in an aqueous/organic biphasic system
Abstract

A simple, effective and reversible aqueous/organic phase-transfer method for rhodium nanoparticles was developed on the basis of the cloud point (Cp) of thermoregulated ligand. The rhodium nanoparticles stabilized by thermoregulated ligand Ph2P(CH2CH2O)nCH3 (n = 16) could transfer from aqueous phase to 1-butanol phase and vice versa by means of changing temperature. This thermoregulated phase-transfer rhodium nanoparticle catalyst evaluated in the hydrogenation of olefins in an aqueous/1-butanol biphasic system exhibited high activity and stability.

Keywords
Thermoregulated ligand; Rhodium nanoparticles; Hydrogenation; Aqueous/organic biphasic catalysis; Olefin
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Thermoregulated phase-transfer rhodium nanoparticle catalyst for hydrogenation in an aqueous/organic biphasic system
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 11, Issue 6, 20 February 2010, Pages 542–546
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
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