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Immobilization of manganese tetraphenylporphyrin on Au/SiO2 as new catalyst for cyclohexane oxidation with air

Paper ID Volume ID Publish Year Pages File Format Full-Text
51132 46831 2009 4 PDF Available
Title
Immobilization of manganese tetraphenylporphyrin on Au/SiO2 as new catalyst for cyclohexane oxidation with air
Abstract

Manganese tetraphenylporphyrin was successfully immobilized on Au/SiO2, by using mercaptopyridine with sulfhydryl and pyridyl groups as bridging agent. The synthesized catalyst with novel structure was characterized by FTIR spectroscopic technique, XPS measurement, TG–DTA analysis and so on. During aerobic oxidation of cyclohexane in the presence of this material, the conversion of cyclohexane and total selectivity to cyclohexanone and cyclohexanol were up to 5.39% and 88.74%, respectively.

Keywords
Manganese tetraphenylporphyrin; Au/SiO2 catalyst; Air; Oxidation; Cyclohexane
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Immobilization of manganese tetraphenylporphyrin on Au/SiO2 as new catalyst for cyclohexane oxidation with air
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 11, Issue 2, 30 October 2009, Pages 110–113
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
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