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First catalytic application of metal complexes of porpholactone and dihydroxychlorin in the sulfoxidation reaction

Paper ID Volume ID Publish Year Pages File Format Full-Text
51174 46834 2009 4 PDF Available
Title
First catalytic application of metal complexes of porpholactone and dihydroxychlorin in the sulfoxidation reaction
Abstract

Iron and manganese complexes meso-tetraphenylporpholactone, MTPPLX, and meso-tetraphenyl-2,3-dihydroxy-2,3-chlorin, MTPP(OH)2X (X = Cl and (CH3COO)), are efficient catalysts for selective oxidation of sulfides with hydrogen peroxide. The effect of catalyst concentration on the conversion, selectivity and yield of products were studied. The results show that iron and manganese porpholactones and chlorins are a slightly better catalyst than TPP analogues for most sulfide substrates.

Keywords
Tetraphenylporpholactone metal complex, Tetraphenyl-2,3-dihydroxy-2,3-chlorin metal complex, Sulfoxidation, Hydrogen peroxide
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First catalytic application of metal complexes of porpholactone and dihydroxychlorin in the sulfoxidation reaction
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 11, Issue 4, 15 December 2009, Pages 232–235
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
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