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Benzylation of benzene with benzyl chloride on iron-containing mesoporous mordenite

Paper ID Volume ID Publish Year Pages File Format Full-Text
51231 46836 2012 5 PDF Available
Title
Benzylation of benzene with benzyl chloride on iron-containing mesoporous mordenite
Abstract

Microporous mordenite with a low Si/Al ratio was synthesized by using silicic acid powder as silica source under hydrothermal condition. By treating the mordenite with acid and base, mesoporous mordenite (M-Mor) was obtained, which was characterized by X-ray diffraction (XRD), N2 sorption experiments, and scanning electron microscopy (SEM). Based on the M-Mor material, iron-containing mesoporous mordenite (Fe-M-Mor) was prepared by ion-exchanged method. The benzylation of benzene by benzyl chloride showed that Fe-M-Mor was a highly active catalyst in this reaction and could be reused. These results indicate that Fe-M-Mor has potential applications in Friedel–Crafts alkylations, especially of large molecules.

► Iron-containing mesoporous mordenite (Fe-M-Mor) was prepared for the first time. ► Fe-M-Mor showed excellent catalytic performance in the benzylation of benzene and benzyl chloride and could be reused. ► Fe-M-Mor has potential application in Friedel-Crafts alkylations, especially of large molecules.

Keywords
Mesoporous; Mordenite; Iron-containing; Benzyl chloride; Benzylation
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Benzylation of benzene with benzyl chloride on iron-containing mesoporous mordenite
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 28, 5 November 2012, Pages 64–68
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
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Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us