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Gold complex-catalyzed CP bond formation by Kabachnik–Fields reactions

Paper ID Volume ID Publish Year Pages File Format Full-Text
51246 46836 2012 4 PDF Available
Title
Gold complex-catalyzed CP bond formation by Kabachnik–Fields reactions
Abstract

CP bond formation was realized through the three-component reaction of an amine, an aldehyde and a dialkylphosphite catalyzed by gold complex. The corresponding α-aminophosphonates were afforded in one-pot reaction with high yields under mild conditions.

Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slideHighlights► C–P bonds formation was realized through the reaction catalyzed by gold complex. ► Gold-bipy complex show the best catalytic activity. ► Reactions of aldehydes with aromatic amines do not show remarkable difference. ► A plausible mechanism of the reaction is proposed based on some experiments. ► Cleaner conversion, higher yields are some of the advantages of the protocol.

Keywords
Gold complex; Formation of CP bonds; Kabachnik–Fields reactions; α-Aminophosphonate; Dialkylphosphite
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 28, 5 November 2012, Pages 134–137
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us