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An unusual gold-catalyzed rearrangement of α-hydroxy epoxides

Paper ID Volume ID Publish Year Pages File Format Full-Text
51271 46837 2009 4 PDF Available
Title
An unusual gold-catalyzed rearrangement of α-hydroxy epoxides
Abstract

A novel gold-catalyzed rearrangement of α-hydroxy epoxides has been investigated. The reaction proceeds efficiently under mild conditions to afford unsymmetrical 1,5 or 1,6-diketones and monoketones in moderate to high yields. The selective formation of the two products could be controlled by substituents and ring strain.Figure optionsDownload full-size imageDownload as PowerPoint slide

Keywords
Gold; Epoxide; α-Hydroxy epoxide; Rearrangement
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An unusual gold-catalyzed rearrangement of α-hydroxy epoxides
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 10, Issue 14, 25 August 2009, Pages 1824–1827
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
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Price was $35.95
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