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The functionalized ionic liquid-stabilized palladium nanoparticles catalyzed selective hydrogenation in ionic liquid

Paper ID Volume ID Publish Year Pages File Format Full-Text
51286 46837 2009 5 PDF Available
Title
The functionalized ionic liquid-stabilized palladium nanoparticles catalyzed selective hydrogenation in ionic liquid
Abstract

The functionalized ionic liquid (2,3-dimethyl-1-[3-N,N-bis(2-pyridyl)-propylamido] imidazolium hexafluorophosphate, [BMMDPA][PF6]) stabilized and modified palladium nanoparticles were obtained by reducing palladium(II) complex with molecular hydrogen. The as-synthesized palladium nanoparticles have been characterized by different methods. It was demonstrated that the Pd nanoparticles were very efficient catalysts for the selective hydrogenation of the CC bonds of various functionalized alkenes under mild conditions in neat ionic liquid (1-n-butyl-2,3-dimethylimidazolium hexafluorophosphate, [BMMIM][PF6]). An efficient separation of the products from reaction mixture (ionic liquid phase) was realized and the catalyst’s nano-dispersion and high performance could be preserved.

Keywords
Functionalized ionic liquid; Palladium nanoparticles; Selective hydrogenation
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The functionalized ionic liquid-stabilized palladium nanoparticles catalyzed selective hydrogenation in ionic liquid
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 10, Issue 14, 25 August 2009, Pages 1903–1907
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
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Don't Miss Today's Special Offer
Price was $35.95
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