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One-pot synthesis of ethylene glycol and its mono-methyl ether from ethylene using Al-TS-1 catalyst

Paper ID Volume ID Publish Year Pages File Format Full-Text
51292 46837 2009 4 PDF Available
Title
One-pot synthesis of ethylene glycol and its mono-methyl ether from ethylene using Al-TS-1 catalyst
Abstract

Ethylene glycol (EG) and its mono-methyl ether (MME) were synthesized directly from ethylene and hydrogen peroxide under mild conditions using Al–TS-1 as the bifunctional catalyst. The progressive incorporation of Al into the framework increased the catalytic capacity of Al–TS-1 until a maximum was reached (SiO2/Al2O3 molar ratio: 504), whereas further Al incorporation decreased the catalytic activity to even lower values than in TS-1. Under the optimum conditions, the conversion and utilization of H2O2 reached 95% and 90%, respectively, while the total concentration of EG and MME reached to above 10 wt.%.

Keywords
Ethylene; Ethylene glycol; Ethylene glycol mono-methyl ether; Epoxidation; Bifunctional; Al–TS-1
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One-pot synthesis of ethylene glycol and its mono-methyl ether from ethylene using Al-TS-1 catalyst
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 10, Issue 14, 25 August 2009, Pages 1936–1939
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us