fulltext.study @t Gmail

Palladium catalysis in reductive alkyl group transfer from trialkylamines to nitroarenes followed by cyclization

Paper ID Volume ID Publish Year Pages File Format Full-Text
51301 46838 2009 4 PDF Available
Title
Palladium catalysis in reductive alkyl group transfer from trialkylamines to nitroarenes followed by cyclization
Abstract

Nitroarenes having electron donating and withdrawing substituents are reductively cyclized with an array of trialkylamines in the presence of a catalytic amount of Pd/C along with tin(II) chloride at 120 °C in a toluene/H2O medium to afford quinolines in moderate to good yields. The product yield depends on the position of the substituent of nitroarenes and the chain length of trialkylamines. The addition of tin(II) chloride is essential for the formation of quinolines and toluene/H2O is the solvent of choice.

Keywords
Alkyl group transfer; Cyclization; Nitroarenes; Palladium catalyst; Quinolines; Trialkylamines
First Page Preview
Palladium catalysis in reductive alkyl group transfer from trialkylamines to nitroarenes followed by cyclization
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us
Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 10, Issue 11, 10 June 2009, Pages 1482–1485
Authors
, , ,
Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us