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Facile preparation of hydrocarbon fuel-soluble nano-catalyst and its novel application in catalytic combustion of JP-10

Paper ID Volume ID Publish Year Pages File Format Full-Text
51309 46838 2009 5 PDF Available
Title
Facile preparation of hydrocarbon fuel-soluble nano-catalyst and its novel application in catalytic combustion of JP-10
Abstract

Hexanethiol monolayer protected palladium clusters (Pd MPCs), which can be well dispersed in hydrocarbon fuels at nanometer scale (<1.5 nm) were synthesized and characterized by TGA, DTA, NMR, FTIR, TEM and microcoulomb sulfur analysis. The particle size and thermal stability of Pd MPCs were sensitive to the thiol/Pd mole ratio in the initial reaction mixture. Moreover, Pd MPC was introduced to improve the combustion of JP-10 (exo-tetrahydrodicyclopentadiene). The results showed that the addition of 50 ppm catalyst in JP-10 could reduce the temperature required to initiate combustion by about 240 °C.

Keywords
Monolayer protected cluster; JP-10 catalytic combustion; Soluble nano-catalyst
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Facile preparation of hydrocarbon fuel-soluble nano-catalyst and its novel application in catalytic combustion of JP-10
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 10, Issue 11, 10 June 2009, Pages 1518–1522
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us