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Copper(II)-coordinated organic nanotube: A novel heterogeneous catalyst for various oxidation reactions

Paper ID Volume ID Publish Year Pages File Format Full-Text
51355 46840 2010 5 PDF Available
Title
Copper(II)-coordinated organic nanotube: A novel heterogeneous catalyst for various oxidation reactions
Abstract

Copper(II)-coordinated organic nanotube can function as a heterogeneous catalyst for oxidation of a variety of organic compounds in the presence of hydrogen peroxide and tert-butyl hydroperoxide. The morphology of this catalyst remained same before and after the oxidation reactions. The catalyst can be reused for several times. In the presence of hydrogen peroxide, Copper(II)-coordinated organic nanotube formed a stable brown color peroxo bridge intermediate. But such intermediate did not form with tert-butyl hydroperoxide.

Graphical AbstractCopper (II)-coordinated organic nanotube with atom-efficient oxidants can function as a heterogeneous catalyst for various oxidation reactions. This catalyst holds great promise due to its excellent reusability property.Figure optionsDownload full-size imageDownload as PowerPoint slideResearch highlights►Copper(II)-coordinated organic nanotube showed unique catalytic activity for oxidation of variety of organic compounds in the presence of atom efficient oxidants due to the large surface area of the nanotube.

Keywords
Copper(II)-coordinated organic nanotube; Heterogeneous catalyst; Oxidation of various organic compounds; Reusability; Peroxo bridge nano-intermediate
First Page Preview
Copper(II)-coordinated organic nanotube: A novel heterogeneous catalyst for various oxidation reactions
Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 12, Issue 1, 25 October 2010, Pages 9–13
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis