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Oxidation of benzothiophene by tert-butyl hydroperoxide over vanadia–alumina catalyst: An FT-IR study at the vapour–solid interface

Paper ID Volume ID Publish Year Pages File Format Full-Text
51387 46842 2009 4 PDF Available
Title
Oxidation of benzothiophene by tert-butyl hydroperoxide over vanadia–alumina catalyst: An FT-IR study at the vapour–solid interface
Abstract

The adsorption and coadsorption of tert-butyl hydroperoxide and benzothiophene vapours over vanadia–alumina catalysts has been investigated by FT-IR spectroscopy. The formation of surface tert-butyl-peroxide species has been observed. These species oxidize benzothiophene to the corresponding sulphones at room temperature (r.t.). Sulphoxides are not observed.

Keywords
Vanadia–alumina; Benzothiophene; tert-Butyl-peroxide; Oxidation; Desulphurization; Infrared spectroscopy; Oxidative desulphurization
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Oxidation of benzothiophene by tert-butyl hydroperoxide over vanadia–alumina catalyst: An FT-IR study at the vapour–solid interface
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 10, Issue 13, 25 July 2009, Pages 1629–1632
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
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Any Questions? feel free to contact us