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Alkene epoxidation catalyzed by molybdenum supported on functionalized MCM-41 containing N–S chelating Schiff base ligand

Paper ID Volume ID Publish Year Pages File Format Full-Text
51446 46843 2009 6 PDF Available
Title
Alkene epoxidation catalyzed by molybdenum supported on functionalized MCM-41 containing N–S chelating Schiff base ligand
Abstract

Efficient epoxidation of olefins catalyzed by MoO2(acac)2 supported on functionalized MCM-41 containing N–S chelating Schiff base ligand, MCM-41-SB-MoO2(acac), is reported. The catalyst, MCM-41-SB-MoO2(acac), can be successfully applied for efficient epoxidation of olefins with tert-BuOOH in 1,2-dichloroethane as solvent. This catalyst was characterized by elemental analysis, FT-IR spectroscopy and X-ray diffraction (XRD). This heterogeneous catalyst can be reused several times without significant loss of its catalytic activity.

Keywords
Supported catalyst; Epoxidation; Molybdenyl acetylacetonate; MCM-41; Schiff base
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Alkene epoxidation catalyzed by molybdenum supported on functionalized MCM-41 containing N–S chelating Schiff base ligand
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 10, Issue 6, 15 February 2009, Pages 853–858
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
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