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Novel pyridine-phosphite ligands for Pd-catalyzed asymmetric allylic substitution reaction

Paper ID Volume ID Publish Year Pages File Format Full-Text
51465 46843 2009 5 PDF Available
Title
Novel pyridine-phosphite ligands for Pd-catalyzed asymmetric allylic substitution reaction
Abstract

A series of novel chiral pyridine-phosphite ligands, synthesized from PCl3, chiral BINOL and 4H-quinolyl alcohols, have been successfully applied in the Pd-catalyzed asymmetric allylic substitution reaction, which afforded the substituted products with high enantioselectivities (up to 95% ee).

Keywords
Pyridine-phosphite ligand; Allylic substitution; Asymmetric catalysis; Palladium
First Page Preview
Novel pyridine-phosphite ligands for Pd-catalyzed asymmetric allylic substitution reaction
Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 10, Issue 6, 15 February 2009, Pages 950–954
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis