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Immobilization of bis(imino)pyridine iron complexes onto mesoporous molecular sieves and their catalytic performance in ethylene oligomerization

Paper ID Volume ID Publish Year Pages File Format Full-Text
51507 46844 2009 5 PDF Available
Title
Immobilization of bis(imino)pyridine iron complexes onto mesoporous molecular sieves and their catalytic performance in ethylene oligomerization
Abstract

Bis(imino)pyridine iron complexes were supported on MAO-treated mesoporous molecular sieves MCM-41 and SBA-15. The effects of reaction temperature and Al/Fe mole ratio on ethylene oligomerization were investigated in detail. The supported complexes, upon activation with MAO, exhibited good catalytic performance towards ethylene oligomerization and formed linear α-olefins at high reaction temperatures. MCM-41 with relatively narrow pore size tended to produce more lower molar mass α-olefins possibly due to more remarkable confinement effects.

Keywords
Immobilization; Mesoporous molecular sieves; Ethylene; Oligomerization
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Immobilization of bis(imino)pyridine iron complexes onto mesoporous molecular sieves and their catalytic performance in ethylene oligomerization
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 10, Issue 10, 20 May 2009, Pages 1467–1471
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
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