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Room temperature efficacious synthesis of diphenylmethane over Fe/Al-MCM-41 catalysts

Paper ID Volume ID Publish Year Pages File Format Full-Text
51512 46845 2010 4 PDF Available
Title
Room temperature efficacious synthesis of diphenylmethane over Fe/Al-MCM-41 catalysts
Abstract

Fe/Al-MCM-41 (Si/Al = 25, 50, 75 and 100) were synthesized. Their catalytic activity was evaluated towards benzylation of benzene with benzyl chloride in liquid phase. The catalytic activity of Fe/Al-MCM-41(25) was higher than the other catalysts. Diphenylmethane(DPM) was obtained as the major product with 100% selectivity and with 100% conversion of benzyl chloride under optimum condition. The effect of temperature and the feed ratio, on the activity of Fe/Al-MCM-41(25) and selectivity towards DPM was studied and a possible reaction mechanism was proposed.

Keywords
Diphenylmethane(DPM); Benzyl chloride(BC); Al-MCM-41; Benzylation; Mesoporous materials; Iron
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Room temperature efficacious synthesis of diphenylmethane over Fe/Al-MCM-41 catalysts
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 11, Issue 10, 11 May 2010, Pages 876–879
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us