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Ionic liquid as catalytic and reusable media for cyanoethoxycarbonylation of aldehydes

Paper ID Volume ID Publish Year Pages File Format Full-Text
51519 46845 2010 6 PDF Available
Title
Ionic liquid as catalytic and reusable media for cyanoethoxycarbonylation of aldehydes
Abstract

Various ionic liquids (IL 1–9) based on N-methyl N′-alkyl imidazolium salts were explored as catalytic media in cyanoethoxycarbonylation of various aldehydes. The study revealed that the alkyl chain length and counter ion of the ionic liquid are critical for the product yield. The highest product yield of cyanohydrin carbonate (up to 96%) was obtained with C5 alkyl chain with Br− as counter ion (IL 3). On the other hand PF6− as counter ion failed to catalyze the cyanoethoxycarbonylation reaction.

Keywords
Cynoethoxycarbonylation; Aldehydes; Ionic liquid; Solvent free; Ethylcyanoformate; Catalysis
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Ionic liquid as catalytic and reusable media for cyanoethoxycarbonylation of aldehydes
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 11, Issue 10, 11 May 2010, Pages 907–912
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us