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Novel dicopper(II)-tetracarboxylates as catalysts for selective oxidation of benzyl alcohols with aqueous TBHP

Paper ID Volume ID Publish Year Pages File Format Full-Text
51524 46845 2010 4 PDF Available
Title
Novel dicopper(II)-tetracarboxylates as catalysts for selective oxidation of benzyl alcohols with aqueous TBHP
Abstract

A few dicopper(II) tetracarboxylate complexes viz. [Cu2(µ-O2CC6H5)4(4-Etpy)2] (1), [Cu2(µ-O2CC6H5)4(4-DMAP)2] (2), [Cu2(µ-O2CC6H5)4(4-CNpy)2] (3) and [Cu2(µ-O2CCH3)4(4-CNpy)2] (4) have been utilised as catalysts for oxidation of benzyl alcohols using aqueous tert-butyl hydroperoxide as the oxidant. Complexes 1 and 2 have shown better catalytic activity than the other two. Unlike other catalysts, these dicopper complexes can catalyse oxidation of alcohols at a very low concentration (0.5 mol%).

Keywords
Cu(II) carboxylate; Copper catalyst; Alcohol oxidation; TBHP
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Novel dicopper(II)-tetracarboxylates as catalysts for selective oxidation of benzyl alcohols with aqueous TBHP
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 11, Issue 10, 11 May 2010, Pages 932–935
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
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